名 师 讲 座(第2期)
题 目: Gold Catalysis: Recent Advances in Transforming π Systems
讲座人: Professor Liming Zhang
University of California, Santa Barbara
时 间: 6月12日(周二)上午10:00-11:30
地 点: 卢嘉锡楼202报告厅
嘉宾简介:
Liming Zhang(张立明教授),现任美国UCSB教授。2003年于密歇根大学获博士学位,2003-2005年于芝加哥大学从事博士后研究。2008 Amgen Young Investigator’s Award,2008 NSF CAREER Award,2009 CAPA Distinguished Junior Faculty Award,2009 Alfred P. Sloan Research Fellow,2014年入选Elsevier高被引学者。
报告摘要:
This talk will discuss the recent developments in our lab on three areas of homogeneous gold catalysis, all of which employ π systems such as alkynes or allenes as substrates. They are: a) insertions into unactivated C-H bonds by in-situ generated acceptor/acyl gold carbenes via oxidative gold catalysis; b) insertions into unactivated C-H bonds by reactive gold vinylidene intermediates en route to versatile 2-bromocyclopentenones; c) the development of new bifunctional phosphine ligands specifically designed for homogeneous gold catalysis and their applications in novel and/or highly efficient gold catalysis.
biwn必赢
2018年6月5日