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摘要:
Energy transfer and light harvesting are important for photocatalysis. The sunlight energy is abundant but diffusive with a typical visible photon density of ~ 1 photon/nm2/ms, leading to a maximum photoelectron generation rate of ~ 1 ms-1 on a single molecular photosensitizer. However, many of the energy storing reactions involves multiple electrons. Green plants use an antenna system with connected chromophore arrays to capture the sunlight energy in a much larger area to support a single reaction centre. Multiple electron/hole injection becomes facile thanks to the light-harvesting network. Two-dimensional analogues, the metal-organic layers (MOLs) are ideal crystalline models to mimic the light-harvesting system in nature to efficiently transfer energy to reaction centres attached to the 2D film and drive energy gaining reactions.
个人简历:
北京大学学士毕业后(2009,林建华教授,李国宝副教授)在美国北卡罗莱那大学教堂山分校获得博士学位(2013,林文斌教授),开展MOF催化研究。之后在芝加哥大学开展博士后研究,从事飞秒超快光谱(2013-2015,Greg Engel教授)。2015.07-至今在厦门大学任教授
此前在J. Am. Chem. Soc., Angew. Chem. Int. Ed.等期刊上发表论文50余篇,论文他引6000余次。课题组目前主要研究方向为二维金属有机单层作为单催化位点催化剂。
参考文献:
J. Am. Chem. Soc. 2019, 141, 44, 17875-17883; J. Am. Chem. Soc. 2020, 142,1,75-79 Nano Research, ASAP, 1-6 DOI :10.1007/s12274-020-2698-8; Nature Catalysis 2019, 2, 709-717 Chem. Commun., 2019, 55, 9657-9660; Inorg. Chem. 2018, 57, 24, 15123-15132; ACS Appl. Mater. Interfaces, 2018, 24, 36290-36296; J. Am. Chem. Soc. 2017, 139, 7020; Angew. Chem. Int. Ed. 2017, 56, 9740; J. Am. Chem. Soc. 2017, 139, 3834; Angew. Chem. Int. Ed. 2016, 55,4962; J. Am. Chem. Soc. 2016, 138, 5308